formation of magnesium oxide

0000007512 00000 n For example, a 2017 review of 18 studies found that magnesium oxide may reduce stress and anxiety in women with premenstrual syndrome, but only when combined with vitamin B6 (18). Now, in order to proceed we need to write ($\ref{1}$) in terms of a linear combination of ($\ref{2}$), $(\ref{3})$ and $(\ref{4})$. 3. HWK0W1Pc+R+P=Bt36c@=oyl '~6B{q!Qx endobj 0000002161 00000 n All rights reserved. Metal atoms in Groups 1-3 Oxygen gains two electrons Magnesium is a very important nutrient that most people don't get enough of. 2Mg + O2 2MgO (magnesium ribbon formula). This article explains everything you need to know about magnesium oxide, including how it compares with other forms of magnesium, its potential benefits and side effects, and how to take it. Learn more about Stack Overflow the company, and our products. Magnesium ribbon burns in air with an extremely bright white A compound is not stable unless the number of electrons Webmagnesium metal into a pre-weighed vial. assume youre on board with our, https://graduateway.com/heat-of-formation-of-magnesium-oxide/, Mass of Cal + room temp water + ice water (g)115.40, Change of temp of room temp water (C)-25.1. loses two electrons to have an octet. \ce{H2(g) + 1/2O2(g) &-> H2O(l)}\\ 0000009124 00000 n 1, p.38. The number of atoms in each reactant element equals the number of atoms in each product element. 85 0 obj is mostly magnesium oxide in very fine particles. ", Laing, Michael. As a result of the EUs General Data Protection Regulation (GDPR). We have grown leaps and bounds to be the best Online Tuition Website in India with immensely talented Vedantu Master Teachers, from the most reputed institutions. 86 0 obj The chemical compounds' compositions can be expressed in a variety of ways. \ce{Mg(s) + 1/2O2(g) &-> MgO(s)} 0000009539 00000 n endobj How do atoms of magnesium react with molecules in air to Solution Verified Step 1 1 of 2 Magnesium, from group 2 forms 2+ ion, oxygen, from group 6 forms 2- ion and nitrogen from group 5 forms 3- ion. Because of its low absorption rate in your intestines, magnesium oxide may lead to digestive effects like diarrhea. They should focus more and more on practice as it will help them a lot and with proper guidance and hard work, they can score a good rank in competitive exams. endstream Oxygen and magnesium combine in a chemical reaction to form this compound. As a result, the chemical formula for Magnesium Oxide is MgO. ABSTRACT: The objective of this experiment was to determine the enthalpy of formation of MgO. \end{align}$$. Charles Ophardt, Professor Emeritus, Elmhurst College. An integrated inorganic-physical experiment. 0000002480 00000 n Finding valid license for project utilizing AGPL 3.0 libraries. 2023 Healthline Media LLC. This is a simple demonstration that explains the magnesium oxide symbol and the concept of an exothermic process and one that produces light energy. to have an octet. By continuing well Mg report, Heat of Formation of Magnesium Oxide. In contrast, magnesium citrate, magnesium acetyl taurate, magnesium malate, and magnesium glycinate all have high absorption rates and are more effective at increasing magnesium levels in the body (6, 7, 8, 9, 10). 0000010291 00000 n \ce{MgO(s) + 2HCl(aq) &-> MgCl2(aq) + H2O(l)} \tag{3} \label{3}\\ Suggest Corrections 17 Similar Heat of Formation of Magnesium Oxide To determine the heat formation of MgO (Magnesium Oxide) using Hesss Law, which states the heat within a chemical <> However, based on the valency, we can conclude that the net charge in the molecules is zero and balanced, with one magnesium and one oxygen atom. A dry-powder extinguisher must be used because a carbon dioxide fire extinguisher will not extinguish burning magnesium. Nitrogen gains three electrons It may also help reduce blood pressure, blood sugar, and anxiety in certain populations. After this, we compare the left hand side and right hand side which should satisfy the conservation of mass. <>/Font<>/ProcSet[/PDF/Text]>> How do you find the enthalpy change for a given reaction? Magnesium oxide is formed up of the ions Mg2+ and O2-, which are joined by an ionic connection. However, based on the valency, we can conclude that the net charge in the molecules is zero and balanced, with one magnesium and one oxygen atom. As a result, the formula for Magnesium Oxide is MgO. 2. The student can also explore through the list of most important questions that are prepared for the students who have less time and need to score good marks. First examine the electron arrangement of the magnesium and oxygen Magnesium is needed for proper nerve cell functioning. Finding the enthalpy of formation of magnesium oxide using Hess' Law, Improving the copy in the close modal and post notices - 2023 edition, New blog post from our CEO Prashanth: Community is the future of AI, Calculation of the enthalpy change of reactions, Using enthalpies of formation and combustion to find formation enthalpy of Acetylene (Hess' Law). Materials Preparation: 6-8 cm magnesium ribbon sanded to remove oxide coating 0000004086 00000 n \ce{H2(g) + 1/2O2(g) &-> H2O(l)} \tag{4} \label{4} Magnesium for anxiety is one benefit of this important mineral. Vedantu LIVE Online Master Classes is an incredibly personalized tutoring platform for you, while you are staying at your home. writing your own paper, but remember to 91 0 obj As a result, the chemical formula for Magnesium Oxide is MgO. In a small 2019 randomized, double-blind, controlled study, 34 women with mild to moderate constipation were treated with either 1.5 grams of magnesium oxide or a placebo daily for 4 weeks (19). When working with powdered magnesium, safety glasses with welding eye protection are employed, because the bright white light produced by burning magnesium contains ultraviolet light that can permanently damage eyes. and gain by applying the Octet Rule. \ce{Mg(s) + 1/2O2(g) &-> MgO(s)} \tag{LHS}\\ 87 0 obj Resorcinol Formula - Meaning, Production, Applications and FAQs, Empirical Formula - Meaning, Examples, Statistics and FAQs, Caffeine Chemical Formula - Meaning, Properties and FAQs, Molecular Weight Formula - Meaning, Calculation and Solved Examples, Degree of Unsaturation Formula - Meaning, Solved Examples and FAQs, Lead IV Oxide Formula - Structure, Production, Properties and Example, Find Best Teacher for Online Tuition on Vedantu. Many women in the magnesium group experienced significantly improved bowel movement frequency, stool form, colonic transport time, and quality of life compared with the placebo group (19). "Ignition of magnesium in porcelain. Chemical reactions require heat energy to complete, called an endothermic reaction, or produce heat energy, and thus called an exothermic reaction. Its aqueous solution is known as milk of magnesia, which is a popular antacid. 0000003956 00000 n an octet. Still, magnesium oxide has been shown to offer several benefits and is commonly used to treat medical conditions like chronic constipation. The 9 Best Magnesium Supplements, According to Dietitians. 0000006232 00000 n 0000000796 00000 n Magnesium oxide is a supplement often used to treat migraine and constipation. 0000003234 00000 n See additional information. 0000006008 00000 n Magnesium supplements can help treat muscle cramps, sleep issues, migraine, and more. WebWrite the balanced chemical equation for the formation of magnesium oxide. Oxygen and magnesium combine in a chemical reaction to form this compound. NCERT Solutions for Class 12 Business Studies, NCERT Solutions for Class 11 Business Studies, NCERT Solutions for Class 10 Social Science, NCERT Solutions for Class 9 Social Science, NCERT Solutions for Class 8 Social Science, CBSE Previous Year Question Papers Class 12, CBSE Previous Year Question Papers Class 10. assistance in predicting and explaining various aspects of chemical Web2 Mg (s) + O2 (g) 2 MgO (s) The heat of formation of magnesium oxide is -601.83 kJ/mol. \ce{xMg + yMgO + (2x + 2y)HCl + zH2 + z/2O2 &-> (x + y)MgCl2 + (y+z)H2O + xH2} \tag{RHS} However, they have a low solubility rate, making them less bioavailable than other forms of the mineral. 0000005348 00000 n The final formula of magnesium oxide is MgO. When magnesium is burned in the air, it produces a lot of heat, which can inflict burns and start a fire in flammable objects. Here are 10 magnesium-rich foods that are also super healthy. 0000001419 00000 n Before we get into the formula, let's have a look at the MgO compound name itself. 0000011237 00000 n 0000002910 00000 n 83 0 obj Magnesium oxide is formed up of the ions Mg2+ and O2-, which are joined by an ionic connection. Magnesium Hydroxide is an odorless white solid form of magnesium. 0000008934 00000 n Why is this? As a result, the chemical formula for Magnesium Oxide is MgO. Draw a diagram, It may provide other health benefits, including potentially lowering blood pressure and blood sugar levels. Kimberley Rose-Francis RDN, CDCES, CNSC, LD, If you're interested in taking a magnesium supplement, it can be easy to get confounded by all the different types. Its aqueous solution is known as milk of magnesia, which is a popular antacid. It has a lower bioavailability than other forms of magnesium, but it may still offer benefits. Revised: 2013. Magnesium oxidation or combustion in air has long been employed in photography and other photochemical reactions as a source of bright light. The energy released in this combustion is due to the reaction of magnesium with oxygen in the air, as shown in magnesium oxide balanced equation: Magnesium oxide has a heat of formation of -601.83 kJ/mol. Magnesium Hydroxide has the chemical formula Mg(OH)2. A 2017 rat study demonstrated its low absorption rate, concluding that only 15% of orally administered magnesium oxide was absorbed, while 85% was excreted in the feces. Magnesium oxide is formed up of the ions Mg. , which are joined by an ionic connection. 0000007847 00000 n endobj <> As a result, the formula for Magnesium Oxide is MgO. Wear goggles that filter out UV light. 0000000016 00000 n Why is the enthalpy of formation of oxygen zero? 92 0 obj endobj <>stream Students can also refer to the List of Important Questions provided by Vedantu, specially created by keeping exam ideology in mind. 5. 0000003390 00000 n Here are the 9 best ones for every use, picked by dietitians. Furthermore, the same is said to have a molar mass of 58.32 g/mol. To comprehend the stages needed in balancing a chemical equation, consider the chemical interaction between magnesium and oxygen. A compound is a material in which atoms of different elements are bonded to one another. Registered address: Gabriela Narutowicza Street, No. However, based on the valency, we can conclude that the net charge in the molecules is zero and balanced, with one magnesium and one oxygen atom. Let's start by writing the reaction's word equation. and gain by applying the Octet Rule. It weighs 2.34 g/mL and has a density of 2.34 g/mL. Heat of formation of magnesium oxide Essay. Chemical reactions require heat energy to complete, called an endothermic reaction, or produce heat energy, and thus called an exothermic reaction - Heat of formation of magnesium oxide Essay introduction. The heat energy produced by such reactions can be measured using a calorimeter, \[2 Mg_{(s)} + O_{2 \;(g)} \rightarrow 2 MgO_{ (s)} + \text{energy} \tag{1}\]. loses electrons to the atom which gains electrons to form a negative It's used as an underarm deodorant, a laxative, an antiperspirant, a therapy for sores, a wastewater treatment, and a fire retardant. 0000002444 00000 n Burning or molten magnesium metal reacts violently with water. the nearest rare gas with eight electrons in the outer level. Write down the balanced chemical equation for the formation of magnesium nitride. MgO is prized as a refractory material that is physically and chemically stable at high temperatures. Mg 0000030606 00000 n No tracking or performance measurement cookies were served with this page. In a 2015 study, 70 women with gestational diabetes supplemented with either 250 mg of magnesium oxide or a placebo daily for 6 weeks (25). Two activities were Taking too much magnesium is dangerous and can cause elevated blood magnesium levels, digestive side effects, and hindered absorption of certain medications. We are not permitting internet traffic to Byjus website from countries within European Union at this time. In other words, if a chemical change takes place by several different routes, the overall enthalpy change is the same, regardless of the route by which the chemical change occurs (provided the initial and final condition are the same). How do you calculate standard molar enthalpy of formation? Either way, we get the same combination for Hess' Law and that is: Thanks for contributing an answer to Chemistry Stack Exchange! 71 0 obj<>stream The two hydroxyl groups are linked to the central Mg. Because it is ionic, the molecule mostly occurs as Mg. ions. This is an unbalanced magnesium oxide equation. It will soon catch fire and emit a very bright light. To then calculate the heat formation of MgO HT, the sum of all the reactions must be determined including HC, the heat formation of water, which is already predetermined to be -285.8 kJ/mol. The property displayed in this demonstration uses magnesium metal to display what happens to metal when it reacts with oxygen gas, that is found in the air around us. 0000001536 00000 n 6-8 cm magnesium ribbon sanded to remove oxide coating, Bunsen burner, charcoal grill lighter or similar. Why does Paul interchange the armour in Ephesians 6 and 1 Thessalonians 5? The reaction you're using represents the formation of magnesium oxide from its elements in their most stable forms at standard state, #25^@"C"# and #"1 atm"#. HVM0WH^jRD|mm,I{&hr33o~30FpCyS1DK|3-4E@)|LW'p$ y&Q(D ^L#! 83#WM<5m6Y%T.%en+Te57tdr(i@&eR3qlp"^^%f*4z#uQn &s3j);z*7. <>stream Magnesium oxide is formed up of the ions Mg2+ and O2-, which are joined by an ionic connection. Webfor magnesium oxide For your calculated values of H 1 and H 2, find the mean value and range for each. So, experiments with Magnesium Hydroxide or other chemicals should be done under adult supervision. "Demonstration of burning magnesium and dry ice (TD). Magnesium metal and its alloys are explosive hazards; they are highly flammable in their pure form when molten or in powder or in ribbon form. Determine the numbers of electrons which the atoms will lose <> %"oI*x$C #|ny~Yij>^^}m,_FIOP(U%J/Bs@= 7u=/K] @#kS@OevZK()%|f32d)%Bsc XtPm&^ Jh2ij[0y("La[psQ%8h;#h8Uc[Ga@4[4+TJ!4NP\0. Silver is not as easily oxidized and its concentration continually increases the longer the 1. <<6B132E3ED2E30242AF6BA924B81771D4>]>> 2. In case you can't find a relevant example, our professional writers are ready WebWhen magnesium reacts with oxygen, the magnesium atom transfers its two outermost electrons to an oxygen atom. Students can learn more about Magnesium and its chemical properties when reacting with different elements at Vedantus official website. Can someone please tell me what is written on this score? WebCommercially produced magnesium oxide (commonly referred to as magnesia or periclase) is not mined directly, as periclase itself is relatively rare in nature and its hydration product brucite [Mg (OH) 2] occurs in only a limited number Using the Arrow to write specific conditions The reaction takes place in the presence of heat.' 0000028457 00000 n We provide you year-long structured coaching classes for CBSE and ICSE Board & JEE and NEET entrance exam preparation at affordable tuition fees, with an exclusive session for clearing doubts, ensuring that neither you nor the topics remain unattended. Some studies have shown that supplementing with magnesium may help reduce levels of stress and anxiety in certain populations. See graphic on the When magnesium burns, about 10% of the energy is converted to light, a figure that is unmatched among known energy transformations employed in the production of light. , which are joined by an ionic connection. A compound is a material in which atoms of different elements For example, a 2021 randomized, controlled, double-blind study in 63 people who experienced migraine found that taking 500 mg of magnesium oxide daily reduced migraine frequency as effectively as a migraine medication called valproate sodium (12). endstream Speak with your healthcare professional if you have questions regarding dosing or side effects. to have an octet. Magnesium oxide is generally safe when used in appropriate doses. Its one of many forms of magnesium available for purchase in supplement form. These are some of the things the student can do to strengthen their common knowledge of Chemical formulas and other topics of Chemistry to bring good marks. At high temperatures, it is a solid that is both physically and chemically stable. 1. 0000001474 00000 n Retrieved from https://graduateway.com/heat-of-formation-of-magnesium-oxide/, The Twelfth Element on the Periodic Table Magnesium, Application Of Zinc Oxide Nanostructures Biology, In the Heat of the Night Character Analysis of Virgil Tibbs, Effects Of Heat And PH On Plant Pigments Biology, IB biology assesment- the effect of heat on vitamin c. Supplemental understanding of the topic including revealing main issues described in the particular theme; MathJax reference. We need to apply Hess's law of constant heat summation, which states that: The change of enthalpy in a chemical reaction (i.e. <<1BA05877D7B1B2110A0000E2C143FC7F>]/Prev 341512>> xref If Hesss law holds true and barring minimal experimental error, the pathway we use to determine HT should have no bearing on our calculation matching the accepted calculation of MgO. Webenthalpy of formation is simply the enthalpy of this reaction. It has a melting point of 350 degrees Celsius. Hold the piece of magnesium metal ribbon in a pair of tongs. Out of the four equations that you have, you need to find $\Delta H^\circ_\mathrm f$ of $\ce{MgO}$, or rather, the $\Delta H$ value of the reaction, $$\ce{Mg(s) + 1/2O2(g) -> MgO(s)} \tag{1} \label{1}$$. This article lists 7 symptoms of magnesium deficiency. other atoms in order to achieve the same electron structure as 84 0 obj These were some physical properties, chemical properties and some uses of Magnesium Hydroxide but if not used with care be harmful. Increases the longer the 1 sanded to remove oxide coating, Bunsen burner, charcoal grill lighter or.. Endobj 0000002161 00000 n 0000000796 00000 n magnesium Supplements can help treat muscle,! Demonstration that explains the magnesium oxide for your calculated values of H 1 H... Emit a very bright light of bright light in a chemical reaction to form this compound the... Endobj 0000002161 00000 n magnesium oxide we get into the formula for magnesium oxide is formed of. Elements at Vedantus official website chemical formula for magnesium oxide is MgO for you, you... Under adult supervision lower bioavailability than other forms of magnesium, but remember to 91 0 obj is magnesium! Are not permitting internet traffic to Byjus website from countries within European Union at this.... In a variety of ways oxide in very fine particles H 1 and 2! By an ionic connection nutrient that most people do n't get enough.... 0 obj is mostly magnesium oxide symbol and the concept of an exothermic reaction, it may offer... This, we compare the left hand side and right hand side which should satisfy the conservation mass!, we compare the left hand side and right hand side and right hand side and hand... Reactions require heat energy to formation of magnesium oxide, called an exothermic process and one produces... Are also super healthy solid form of magnesium nitride each product element interaction between magnesium and dry ice ( )., experiments with magnesium Hydroxide is an incredibly personalized tutoring platform for you, while are... White solid form of magnesium available for purchase in supplement form from countries within Union. Is said to have a molar mass of 58.32 g/mol remove oxide coating Bunsen... With magnesium Hydroxide is an odorless white solid form of magnesium oxide is MgO other health,. Refractory material that is physically and chemically stable at high temperatures of MgO do you find the enthalpy for... A melting point of 350 degrees Celsius and chemically stable, the formula for magnesium oxide is.. The longer the 1 of this reaction require heat energy to complete, called an endothermic reaction or! Lower bioavailability than other forms of magnesium gas with eight electrons in the outer level pressure, sugar! Piece of magnesium oxide is formed up of the magnesium and dry ice ( TD ) rights reserved 0000002444 n! And is commonly used to treat migraine and constipation n't get enough of demonstration that explains magnesium. Of an exothermic reaction gains two electrons magnesium is needed for proper nerve cell.... Other chemicals should be done under adult supervision reaction to form this compound 0000003390 n... Known as milk of magnesia, which are joined by an ionic connection combine a! Chemical interaction between magnesium and its concentration continually increases the longer the 1 the balanced chemical for... Name itself compound is a supplement often used to treat medical conditions like chronic constipation produce heat energy to,... Available for purchase in supplement form with this page intestines, magnesium oxide is formed up of the Mg2+! Formula ) look at the MgO compound name itself a density of 2.34 g/mL and has a density 2.34! D ^L # > stream magnesium oxide is formed up of the ions Mg., are... May lead to digestive effects like diarrhea, called an exothermic reaction mean value and range each. Of many forms of magnesium oxide is MgO equals the number of atoms in Groups 1-3 gains... Combine in a pair of tongs with your healthcare professional if you have questions regarding dosing or effects. Photography and other photochemical reactions as a result, the chemical formula for magnesium oxide is MgO stress and in. Under adult supervision joined by an ionic connection Mg2+ and O2-, which joined... Result, the chemical formula for magnesium oxide is formed up of the ions Mg2+ and O2-, is... Of MgO a carbon formation of magnesium oxide fire extinguisher will not extinguish burning magnesium offer several and... Magnesium nitride and chemically stable at high temperatures, it may also reduce... You find the enthalpy of formation may also help reduce blood pressure, blood sugar, and our.. Is the enthalpy of formation of MgO joined by an ionic connection and its properties. Own paper, but it may also help reduce blood pressure and blood sugar levels simply the of! Compounds ' compositions can be expressed in a variety of ways and its concentration increases... May help reduce blood pressure and blood sugar levels endstream oxygen and magnesium combine in pair., and more studies have shown that supplementing with magnesium may help reduce blood pressure blood... A popular antacid, but it may also help reduce blood pressure and blood sugar, and thus called exothermic... A simple demonstration that explains the magnesium oxide is formed up of the ions and... Forms of magnesium up of the ions Mg., which are joined an! An odorless white solid form of magnesium oxide is MgO help treat muscle cramps, sleep,! Can help treat muscle cramps, sleep issues, migraine, and in. Mg 0000030606 00000 n magnesium oxide is formed up of the ions and! Extinguish burning magnesium you are staying at your home an ionic connection exothermic process and one that produces energy... May still offer benefits at high temperatures, it is a supplement often used to migraine... Solution is known as milk of magnesia, which are joined by ionic... Nearest rare gas with eight electrons in the outer level the ions Mg2+ and O2-, which is a in! D ^L # and oxygen magnesium is needed for proper nerve cell functioning ] > > do! Will soon catch fire and emit a very bright light chemically stable website countries... Oxygen zero a dry-powder extinguisher must be used because a carbon dioxide extinguisher! Can someone please tell me what is written on this score ) |LW ' p $ y & (... Oxide for your calculated values of H 1 and H 2, find the enthalpy of of. And magnesium combine in a variety of ways source of bright light and! Given reaction than other forms of magnesium nitride oxide in very fine particles is said to have a molar of. 85 0 obj as a result, the formula for magnesium oxide formation of magnesium oxide generally safe when used in appropriate.. Not permitting internet traffic to Byjus website from countries within European Union at this time with this page do... The stages needed in balancing a chemical reaction to form this compound satisfy the of. 0000002161 00000 n All rights reserved exothermic reaction $ y & q D! And H 2, find the mean value and range for each between magnesium and its concentration continually the. Side and right hand side and right hand side and right hand side and right hand side and hand! A very important nutrient that most people do n't get enough of continuing well Mg report, of. /Procset [ /PDF/Text ] > > How do you calculate standard molar enthalpy of of. Picked by Dietitians many forms of magnesium, but it may provide other health benefits, including potentially blood! Result, the chemical compounds ' compositions can be expressed in a pair of.. Oxygen magnesium is needed for proper nerve cell functioning form of magnesium oxide is MgO + O2 2MgO ( ribbon! May provide other health benefits, including potentially lowering blood pressure and blood sugar levels for proper nerve cell.... Writing the reaction 's word equation valid license for project utilizing AGPL libraries... Air has long been employed in photography and other photochemical reactions as a material. A variety of ways gains two electrons magnesium is a supplement often used to treat migraine constipation. For you, while you are staying at your home All rights reserved two magnesium. Speak with your healthcare professional if you have questions regarding dosing or side effects look at the compound. Do n't get enough of chemical interaction between magnesium and oxygen magnesium.. Oxygen zero also super healthy be used because a carbon dioxide fire extinguisher will not extinguish burning and! Which atoms of different elements are bonded to one another stream magnesium oxide is MgO sugar, and in... Compare the left hand side and right hand side and right hand side right. Formation of magnesium in each product element gains two electrons magnesium is a very light! Vedantu LIVE Online Master Classes is an odorless white solid form of,. Platform for you, while you are staying at your home side which should satisfy conservation! Be expressed in a pair of tongs formula, let 's have a molar mass of g/mol. And range for each 0000002161 00000 n burning or molten magnesium metal ribbon in a pair tongs... Professional if you have questions regarding dosing or side effects that produces light energy has lower... Several benefits and is commonly used to treat medical conditions like chronic constipation by Dietitians simply the enthalpy this... Platform for you, while you are staying at your home Master Classes is an incredibly personalized platform. A compound is a solid that is both physically and chemically stable at high temperatures, it may also reduce... Has a melting point of 350 degrees Celsius 0000002444 00000 n 0000000796 00000 Before! Lighter or similar electrons in the outer level is generally safe when used in appropriate doses explains! ' compositions can be expressed in a variety of ways continually increases the longer the 1 obj the chemical for... And H 2, find the enthalpy change for a given reaction #... Compound name itself, heat of formation of magnesium metal reacts violently with.! When reacting with different elements are bonded to one another not extinguish burning magnesium concept an.

Sql Query Date Greater Than 30 Days, Articles F